The combination of aluminium powder and potassium chlorate is unstable, and a poor choice for flash powder that is to be stored for more than a very short period. large amounts of aluminum signicantly increased the specic impulse of a castable composite propellant. The solid fuel in the booster stage of the space shuttle is a mixture of ammonium perchlorate and aluminum powder. The technical scheme of the invention is that the method for recovering ammonium perchlorate and aluminum powder from thermoplastic propellant comprises the following steps, S1, mixing the thermoplastic propellant with the first solvent, heating to prepare a propellant solution, vacuumizing and filtering the propellant solution, and washing with the first solvent to obtain filter residues; wherein the first solvent has a solubility parameter with the thermoplastic propellant of 6.0 (J/cm). The phenomenon can be explained by considering the heat-flux-to-mass ratio: As the particle radius increases the volume (and, therefore, mass and heat capacity) increases as the cube of the radius. - Amonium picrate (picrate . Anal. https://doi.org/10.1134/S0010508220060088. Komodo Ready-to-Use 55 Gallons (Drum) - Advanced Fire Protection - Home Perimeter Shield - Next Generation All Season Fire Retardant - Made in USA . Because flash powder mixtures are so easy to initiate, there is potentially a high risk of accidental explosions which can inflict severe blast/fragmentation injuries, e.g. 4. 7. On March 16, 2009, it was ruled that APCP is not an explosive and that manufacture and use of APCP no longer requires a license or permit from the ATF. Potassium perchlorate must be free of chlorates. A.Dokhan, E. W.Price, J. M.Seitzman, et al., The Effects of Bimodal Aluminum with Ultrafine Aluminum on the Burning Rates of Solid Propellants," Proc. Large quantities are not only more difficult to handle safely, but they place innocent bystanders within the area at risk. The particle size of the perchlorate is not as critical as that of the aluminum component, as much less energy is required to decompose the KClO4 than is needed to melt the aluminum into the liquid state required for the reaction. Certain that I was responsible for the refrigerated shoes, I quickly closed the door and ran upstairs to make sure I had put the babies in their cribs instead of the linen closet.Mary Kay Blakely (20th century). Flash powder and flash powder devices pose exceptionally high risks to children, who typically cannot understand the danger and may be less adept with safe handling techniques. This includes the Space Shuttle missions, in which APCP was used for the two SRBs. 115 (1), 887894 (2014). The passivated magnesium flash powder is stable and safe to store. Large quantities are not only more difficult to handle safely, but they place innocent bystanders within the area at risk. Wang, DQ., Yu, HM., Liu, J. et al. %PDF-1.2 % (c) Why is the aluminum powdered? Which species arc oxidizing agents? This composition, usually in a ratio of 5 parts potassium nitrate, to 3 parts aluminum powder, to 2 parts sulfur, is especially popular with hobbyists. The assembled RMS contains both reusable (typically metal) and disposable components. Ammonium perchlorate composite propellant is typically for aerospace rocket propulsion where simplicity and reliability are desired and specific impulses (depending on the composition and operating pressure) of 180260s (1.82.5km/s) are adequate. Antimony trisulfide may be used as an alternative, and is more stable in storage.[2][3]. 9. Like all mixtures containing chlorates, it is extremely sensitive to friction, impact and ESD, and is considered unsafe in pyrotechnic devices that contain more than a few tens of milligrams of the mixture. The results show that the exothermic peak temperature of the f-Al/AP-based CMDB propellant is lower than that of the s-Al/AP-based CMDB propellant. Large quantities should never be mixed in a single batch. The method of claim 1, wherein: in S2, a sand core funnel is adopted during vacuum filtration, and the aperture of the sand core funnel is 5 +/-1 mu m; the vacuum degree is-0.01 MPa to-0.1 MPa. X.Li, X.Liu, Y.Cheng, et al., Thermal Decomposition Properties of Double-Base Propellant and Ammonium Perchlorate," J.Therm. And it is not more sensitive than ammonal. It provides a great balance of stability and power, and is the composition used in most commercial exploding fireworks. 1. Aluminum or other metals can be added to the propellant mixture as high energy density fuel (from 0% to 20% by mass of the total). composite propellent. The amount of APCP that can be purchased (in the form of a rocket motor reload) correlates to the impulse classification, and therefore the quantity of APCP purchasable by a hobbyist (in any single reload kit) is regulated by the NAR and TRA. It provides a great balance of stability and power, and is the composition used in most commercial exploding fireworks. No matter the quantity, care must always be taken to prevent any electrostatic discharge or friction during mixing or handling, as these may cause accidental ignition. (1) mixing a thermoplastic propellant with a mixed solvent prepared from toluene and hexamethylphosphoramide according to a mass ratio of 1:1, wherein the mixed solvent comprises the following components in parts by mass: 1.5 adding into a container, heating and stirring at 80 for 8 min to prepare a propellant solution; (2) pouring the solution obtained in the step (1) into a sand core funnel with the aperture of 10 mu m, vacuumizing and filtering the propellant solution under the vacuum degree of-0.05 MPa, adding a mixed solvent of toluene and hexamethylphosphoramide with the mass of 1/3 into the sand core funnel again, filtering and cleaning the solid phase filler, and repeating the operation for three times, wherein the isolate in the sand core funnel is a mixture of AP and Al; (3) and (3) adding ethanol solvent into the funnel separated substance in the step (2), wherein the mass ratio of the solvent to the mixture of AP and Al is 3.0, the vacuum degree is-0.05 MPa, vacuumizing and filtering, adding a mixed solvent of ethanol and tetrahydrofuran with the mass of 1/3 again, filtering and cleaning, and repeating for three times. For photographic use, mixtures containing magnesium and nitrates are made much more fuel rich. The effective oxygen content of AP is almost the highest among oxidants, and the oxygen balance reaches +34.04%, which is beneficial to the oxidation and combustion of other components in the solid propellant. The thermoplastic propellant is a high-molecular energy-containing composite material which takes a thermoplastic elastomer as a matrix and takes Ammonium Perchlorate (AP) and aluminum powder (Al) as solid-phase fillers, has the characteristics of thermoplastic plastics and thermosetting rubber, shows the elasticity of the rubber at normal temperature, shows a viscous flow state like plastics . The propellant they used was 21 percent aluminum, 59 percent ammonium perchlorate, and 20 percent plasticized polyvinyl chloride. The resulting cured propellant is fairly elastic (rubbery), which also helps limit fracturing during accumulated damage (such as shipping, installing, cutting) and high acceleration applications such as hobby or military rocketry. This isn't to say that APCP cannot cause an explosion, just that it will not detonate. 3. 3. In the presence of a catalyst, the mixture forms solid aluminum oxide and aluminum chloride and gaseous water and nitrogen monoxide.A. Tax calculation will be finalised during checkout. Both agencies set forth rules regarding the impulse classification of rocket motors and the level of certification required by rocketeers in order to purchase certain impulse (size) motors. W.Zheng, J.Wang, X.Ren, et al., An Investigation on Thermal Decomposition of DNTFCMDB Propellants," Propell., Explos., Pyrotech. Write the molecular equation for the reaction, (b) In the reaction, which elements are oxidized, and which element is reduced? 42, 253257 (2013). 5. (d) Ammonium perchlorate is made by a precipitation reaction between solutions of sodium perchlorate and ammonium chloride. 22, 151169 (2004). . FIG. It differs from many traditional solid rocket propellants such as black powder or zinc-sulfur, not only in chemical composition and overall performance but also by the nature of how it is processed. Then, these two kinds of aluminum powders are used to prepare ammonium perchlorate-based composite modified double-base (AP-based CMDB) propellants. Sci. This test allows the APCP manufacturer to characterize the burn rate as a function of pressure. Flash powders even within intended usages often release explosive force of deadly capacity. Box Atomized Glitter Aluminum Powder - Uncoated, 23 Micron (5-Pound Unit) $18.50 /lb Magnesium-Aluminum, (Magnalium) -10+50 mesh + turnings $18.40 /lb "ammonium perchlorate" Reverso Context ( - ): The class 1.3, fire hazard but very difficult to impossible to detonate; an example is 70% ammonium perchlorate, 16% aluminium, and 14% binder. Calorim.119 (1), 659670 (2015). Part (b) requires the same steps as part (a), except you are converting the mass of Al to Al2O3, so you use a different mole ratio. The impact and friction sensitivities of the propellant decrease by 12% and 187% after using f-Al to replace s-Al. How many moles of gaseous products were formed from each mole of ammonium perchlorate that exploded? The method of claim 1, wherein: the temperature is controlled to be 60-120 during heating in S3. Curing agent The curing agent is also an integral part of the adhesive system. K.Moore, M. L.Pantoya, and S. F.Son, Combustion Behaviors Resulting from Bimodal Aluminum Size Distributions in Thermites," J.Propul. HIBEX used what is essentially a precursor to modern APCP (Ammonium Perchlorate Composite Propellant), which is widely used in amateur rocketry and commercially available. Fuels for composite propellants are generally metallic powders, with aluminum being the most common. It differs from many traditional solid rocket propellants such as black powder or zinc-sulfur, . . Moon burner: off-center circular bore produces progressive-regressive long burn though has slight asymmetric CG characteristics. Its propellant included Ammonium Perchlorate, Aluminum, Ballistite (powdered nitroglycerine, basically) and zirconium. The propellant is most often composed of ammonium perchlorate (AP), an elastomer binder such as hydroxyl-terminated polybutadiene (HTPB) or polybutadiene acrylic acid acrylonitrile prepolymer (PBAN), powdered metal (typically aluminium), and various burn rate catalysts. (m/s): Several geometric configurations are often used depending on the application and desired thrust curve: While the surface area can be easily tailored by careful geometric design of the propellant, the burn rate is dependent on several subtle factors: In summary, however, most formulations have a burn rate between 13mm/s at STP and 612mm/s at 68 atm. Normally, flash powder mixtures are compounded to achieve a particular purpose. Further, the temperature is controlled to be 60-120 during heating in S2. Aluminium combustion inside the motor is the rate-limiting pathway since the liquid-aluminium droplets (even still liquid at temperatures 3000 K) limit the . View the primary ISBN for: Problem 135A: The reaction of ammonium perchlorate and powdered aluminum in the booster rockets provides the energy to launch the space shuttle, (a) The products of the reaction of ammonium perchlorate and powdered aluminum are aluminum oxide, aluminum chloride, nitric oxide, and water. I have found an unverified reference saying that APCP burns 2X hotter than KNSU, which would put it into 1500C range. Write a balanced equation for the reaction, assign oxidation states This problem has been solved! K.Gnanaprakash, S. R.Chakravarthy, and R.Sarathi, Combustion Mechanism of Composite Solid Propellant Sandwiches Containing Nano-Aluminium," Combust. 3 is a schematic diagram of recovery of aluminum powder as a thermoplastic propellant, wherein a is the filtration separation of aluminum powder; and b is the aluminum powder obtained by recovery. 4.5 out of 5 stars 165. 39 (6), 874880 (2014). Calorim. Magnesium based compositions degrade over long periods, meaning the metallic Mg will slowly react with atmospheric oxygen and moisture. In addition, the burning rate of the f-Al/AP-based CMDB propellant is 5.5% higher. Additionally, the mixture should be made immediately before use. Burn rate catalysts determine how quickly the mixture burns. (Note: 25 grams of mixture is enough to explode in open air without constraint other than air pressure.). Combustion, Explosion, and Shock Waves (Note: 3grams of mixture is enough to explode in open air without constraint other than air pressure.). Space shuttle SRB motor consists of ammonium perchlorate (oxidizer, 69.6% by weight), aluminum (fuel, 16%), iron oxide (a catalyst, 0.4%), a polymer (such as PBAN or HTPB, serving as a binder that holds the mixture together and acting as secondary fuel, 12.04%), and an epoxy curing agent (1.96%). The products were nitric oxide, chlorine, oxygen, and water vapor. Combust. The excess magnesium is volatilized by the reaction and burns in air providing additional light. 1:608 1956]. ), How to make a New Post (submit a question) and use Equation Editor (click for details), How to Subscribe to a Forum, Subscribe to a Topic, and Bookmark a Topic (click for details), Multimedia Attachments (click for details), Bohr Frequency Condition, H-Atom , Atomic Spectroscopy, Heisenberg Indeterminacy (Uncertainty) Equation, Wave Functions and s-, p-, d-, f- Orbitals, Electron Configurations for Multi-Electron Atoms, Polarisability of Anions, The Polarizing Power of Cations, Interionic and Intermolecular Forces (Ion-Ion, Ion-Dipole, Dipole-Dipole, Dipole-Induced Dipole, Dispersion/Induced Dipole-Induced Dipole/London Forces, Hydrogen Bonding), *Liquid Structure (Viscosity, Surface Tension, Liquid Crystals, Ionic Liquids), *Molecular Orbital Theory (Bond Order, Diamagnetism, Paramagnetism), Coordination Compounds and their Biological Importance, Shape, Structure, Coordination Number, Ligands, *Molecular Orbital Theory Applied To Transition Metals, Properties & Structures of Inorganic & Organic Acids, Properties & Structures of Inorganic & Organic Bases, Acidity & Basicity Constants and The Conjugate Seesaw, Calculating pH or pOH for Strong & Weak Acids & Bases, Chem 14A Uploaded Files (Worksheets, etc. Are they still around here? V. A.Babuk, V. A.Vasiliev, and V. V.Sviridov, Propellant Formulation Factors and Metal Agglomeration in Combustion of Aluminized Solid Rocket Propellant," Combust. Further, the thermoplastic propellant is one or more of styrene thermoplastic propellant, polyolefin thermoplastic propellant and polyurethane thermoplastic propellant. Tell you what, I'll make up some, document the aluminum %, and see when it becomes sensitive to a .22 subsonic. Due to these attributes, widespread adoption of APCP and related propellant types in the hobby has significantly enhanced the safety of rocketry. X. L.Xing, F. Q.Zhao, S. N.Ma, et al., Thermal Decomposition Behavior, Kinetics, and Thermal Hazard Evaluation of CMDB Propellant Containing CL-20 by Microcalorimetry," J.Therm. V. K.Bhat, H.Singh, R. R.Khare, et al., Burning Rate Studies of Energetic Double Base Propellants," Def. Preparation of aluminium boride by powder technology. 89, 3546 (2015). Flash powder compositions are also used in military pyrotechnics when production of large amount of noise, light, or infrared radiation is required, e.g., missile decoy flares and stun grenades. The motor casing and closures are typically bought separately from the motor manufacturer and are often precision-machined from aluminium. https://doi.org/10.1134/S0010508220060088, DOI: https://doi.org/10.1134/S0010508220060088. S2, mixing the filter residue obtained in the step S1 with a second solvent, carrying out vacuum filtration again and washing with the second solvent, wherein the filter residue is aluminum powder, and the filtrate is reserved; s3, heating the filtrate obtained in the step S2 to remove the second solvent, and obtaining the ammonium perchlorate. Aluminum powder generally accounts for 50-20% of solid rocket propellant. Hobbyist pyrotechnicians usually use a method called diapering, in which the materials are poured separately onto a large piece of paper, which is then alternately lifted at each corner to roll the composition over itself and mix the components. The vendor is charged with the responsibility (by the NAR and TRA) to check hobbyists for high-power rocket certification before a sale can be made. Further, the second solvent is one or more of acetone, distilled water, ethanol, petroleum ether and tetrahydrofuran. First, convert 1.325 kg of NH4ClO4 into grams by multiplying by 1000. Sometimes, sulfur is included in the mixture to increase the sensitivity. In the event of accidental ignition, debris from a multiple-pound flash powder explosion can be thrown hundreds of feet with sufficient force to kill or injure. It provides a great balance of stability and power, and is the composition used in most commercial exploding fireworks. For best results, "German Dark" aluminum should be used, with air float sulfur, and finely ball-milled pure potassium nitrate. Explosions have . Calorim. Method for recovering ammonium perchlorate and aluminum powder from thermoplastic propellant, Application filed by Hubei Sanjiang Aerospace Jianghe Chemical Technology Co Ltd, Hubei Sanjiang Aerospace Jianghe Chemical Technology Co Ltd, NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C, Oxides or oxyacids of halogens; Salts thereof, ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON, WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H, Recovery or working-up of waste materials, Recovery or working-up of waste materials of polymers, Recovery or working-up of waste materials of polymers without chemical reactions, Recovery or working-up of waste materials of polymers without chemical reactions using selective solvents for polymer components, METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS, PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS, Obtaining aluminium by wet processes from waste materials, Working up raw materials other than ores, e.g. In addition, the higher concentration of fuel results in a slower burn, providing more of a "poof" and less of a "bang" when ignited. Better reference is needed, of course. Ammonium perchlorate composite propellant (APCP) is a solid-propellant rocket fuel. Which species arc oxidizing agents? Upon ignition, the reaction that takes place is 6NH4ClO4(s)+10Al(s)5Al2O3(s)+3N2(g)+6HCl(g)+9H2O(g). I know of more than one person who has failed to do this and learned not to do it again by receiving a face full of AP/AL fire. (d) Ammonium perchlorate is made by a precipitation reaction between solutions of sodium perchlorate and ammonium chloride. C-slot: propellant with large wedge cut out of the side (along axial direction), producing fairly long regressive thrust, though has thermal difficulties and asymmetric CG characteristics. Furthermore, a sand core funnel is adopted during vacuum filtration in S2, and the aperture of the sand core funnel is 5 +/-1 mu m; the vacuum degree is-0.01 MPa to-0.1 MPa. 115 (2), 12271234 (2014). $22.00 $ 22. Lett.3 (2), 253255 (2003). The question gives us 1.325 kg of NH4ClO4 and is asking us to solve for the amount of Aluminum needed for the reaction. . 10. In this paper, two kinds of flake aluminum powder are prepared by bidirectional rotation mill using the spherical aluminum powder (Al-1) as raw materials. These mixtures range from extremely fast-burning mixtures designed to produce a maximum audio report, to mixtures designed to burn slowly and provide large amounts of illumination, to mixtures that were formerly used in photography. Some flash powder formulations (those that use single-digit micrometre flake aluminium powder or fine magnesium powder as their fuel) can self-confine and explode in small quantities. 6. Ammonium perchlorate | NH4ClO4 - PubChem Ammonium perchlorate | NH4ClO4 or ClH4NO4 | CID 24639 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Compacted black powder slugs become prone to fracture in larger applications, which can result in catastrophic failure in rocket vehicles. The method according to any one of claims 1-9, wherein: the thermoplastic propellant is one or more of styrene thermoplastic propellant, polyolefin thermoplastic propellant and polyurethane thermoplastic propellant. [4] Modern recreations of photographic flash powders may avoid the use of barium salts because of their toxic nature. For RMS, the APCP "grains" (cylinders of propellant) are loaded into the reusable motor casing along with a sequence of insulator disks and o-rings and a (graphite or glass-filled phenolic resin) nozzle. - Amonium perchlorate . (m2), propellant density The perchlorate serves as the oxidizer, while the binder and aluminium serve as the fuel. In addition, the chemical composition of the gases changes, varying the effective heat capacity of the gas. 36, No. A flake aluminum powder (f-Al) is prepared by a bi-directional rotation mill method using a spherical aluminum powder (s-Al) as a raw material. Some amateur pyrotechnicians choose to mix the composition by shaking in a closed paper container, as this is much quicker and more effective than diapering. What can you conclude about the relative solubility of ammonium perchlorate? Certain formulations prominent in the underground press contain both sulfur and potassium chlorate. All the data is for stainless steel. 36, 7175 (2014). Learn more about Institutional subscriptions. Anal. ), Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams, Work, Gibbs Free Energy, Cell (Redox) Potentials, Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH), Interesting Applications: Rechargeable Batteries (Cell Phones, Notebooks, Cars), Fuel Cells (Space Shuttle), Photovoltaic Cells (Solar Panels), Electrolysis, Rust, Kinetics vs. Thermodynamics Controlling a Reaction, Method of Initial Rates (To Determine n and k), Arrhenius Equation, Activation Energies, Catalysts, Chem 14B Uploaded Files (Worksheets, etc. Aluminum is the most abundant metal on Earth. 2023 Springer Nature Switzerland AG. The invention provides a method for recovering ammonium perchlorate and aluminum powder from a thermoplastic propellant, which is simple to operate and high in recovery rate. H.E.Kissinger, Reaction Kinetics in Differential Thermal Analysis," J.Anal. - 69.163.236.199. Sulfur is deliberately added as a third component to this mixture in order to reduce the activation energy. 261289 (2001). The main solid ingredients of composite propellant are ammonium perchlorate (AP) and aluminium powder. When mixed, the transportation, storage, usage, various possession, and illegal "firearms" laws (including felonies) may come into effect that do not apply to the unmixed or pre-assembled components. This effect is often mitigated by reducing aluminium particle size, inducing turbulence (and therefore a long characteristic path length and residence time), and/or by reducing the aluminium content to ensure a combustion environment with a higher net oxidizing potential, ensuring more complete aluminium combustion. In the event of accidental ignition, debris from a multiple-pound flash powder explosion can be thrown hundreds of feet with sufficient force to kill or injure. It is used in analytical chemistry and as an etching and engraving agent. A flash composition designed specifically to generate flares that are exceptionally bright in the infrared portion of the spectrum use a mixture of pyro-grade magnesium and powdered polytetrafluoroethylene. Although this composition is fairly insensitive, it should be treated with care and respect. 6. A white, crystalline solid or powder. Comparative example 1: the main operation was the same as in example 4 except that only N, N-dimethylformamide was added in the step (1), and the recovery of AP was finally obtained as 82.6%. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Beginners should start with sub-gram quantities, and refrain from making large devices. This makes flash powder dangerous to handle, as it can cause severe hearing damage and amputation injury even when sitting in the open. ), Administrative Questions and Class Announcements, *Making Buffers & Calculating Buffer pH (Henderson-Hasselbalch Equation), *Biological Importance of Buffer Solutions, Equilibrium Constants & Calculating Concentrations, Non-Equilibrium Conditions & The Reaction Quotient, Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions, Reaction Enthalpies (e.g., Using Hesss Law, Bond Enthalpies, Standard Enthalpies of Formation), Heat Capacities, Calorimeters & Calorimetry Calculations, Thermodynamic Systems (Open, Closed, Isolated), Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric), Concepts & Calculations Using First Law of Thermodynamics, Concepts & Calculations Using Second Law of Thermodynamics, Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy, Entropy Changes Due to Changes in Volume and Temperature, Calculating Standard Reaction Entropies (e.g. Ammonium perchlorate composite propellant (APCP) is a solid-propellant rocket fuel. According to the solubility rules (Table 4.4), all sodium and all ammonium salts are soluble. The finished mixture should never be ball milled together. The recovery rate of Al powder is 99.8%, and the recovery rate of AP is 98.3%. 1007 0 obj << /Linearized 1 /O 1011 /H [ 1372 1153 ] /L 771488 /E 10529 /N 11 /T 751228 >> endobj xref 1007 37 0000000016 00000 n 0000001095 00000 n 0000001280 00000 n 0000001313 00000 n 0000002525 00000 n 0000002739 00000 n 0000002808 00000 n 0000002925 00000 n 0000003033 00000 n 0000003167 00000 n 0000003233 00000 n 0000003372 00000 n 0000003514 00000 n 0000003672 00000 n 0000003808 00000 n 0000003945 00000 n 0000004082 00000 n 0000004184 00000 n 0000004284 00000 n 0000004386 00000 n 0000004487 00000 n 0000004586 00000 n 0000004684 00000 n 0000004783 00000 n 0000004883 00000 n 0000004983 00000 n 0000005083 00000 n 0000005231 00000 n 0000005337 00000 n 0000005409 00000 n 0000005519 00000 n 0000006867 00000 n 0000006978 00000 n 0000010150 00000 n 0000010262 00000 n 0000001372 00000 n 0000002501 00000 n trailer << /Size 1044 /Info 1003 0 R /Root 1008 0 R /Prev 751216 /ID[<7c828a098c45592c535218860feb97f6><7c828a098c45592c535218860feb97f6>] >> startxref 0 %%EOF 1008 0 obj << /Type /Catalog /Pages 1004 0 R /Outlines 1012 0 R /Threads 1009 0 R /Names 1002 0 R /OpenAction [ 1011 0 R /XYZ null null null ] /PageMode /UseOutlines >> endobj 1009 0 obj [ 1010 0 R ] endobj 1010 0 obj << /I << /Title (A)>> /F 1023 0 R >> endobj 1042 0 obj << /S 764 /T 1406 /O 1464 /E 1480 /Filter /FlateDecode /Length 1043 0 R >> stream

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